TL;DR Soda goes flat because the carbon dioxide (CO2) dissolved in the liquid escapes into the air, reducing the fizz and altering the taste.
Carbonation Process
Soda is carbonated by dissolving CO2 gas under pressure. When you open a soda bottle or can, the pressure is released, allowing the dissolved CO2 to escape. This process doesn't happen instantly because the CO2 molecules need nucleation sites—tiny imperfections or particles—to form bubbles [1:1]
[1:3]. The gradual escape of CO2 is why soda loses its fizz over time.
Chemical Reactions
CO2 reacts with water to form carbonic acid (H2CO3), which contributes to the soda's taste. As the soda goes flat, this reaction reverses, turning carbonic acid back into CO2 and water, further diminishing the acidity and altering the flavor [1:4]. The loss of carbonation impacts both the taste and mouthfeel, as the acidic balance and fizzy sensation are reduced
[3:1].
Impact of Shaking
Shaking a soda introduces numerous tiny bubbles throughout the liquid, creating more nucleation sites for CO2 to escape rapidly when opened [5:1]
[5:3]. This results in a quick release of gas, often causing the drink to overflow and go flat faster
[5:2]. Shaking also increases the surface area between the gas and liquid, accelerating the equilibrium process
[2:2].
Volume and Pressure Dynamics
As you consume soda from a bottle, the ratio of liquid to air changes, affecting how much CO2 can remain dissolved. With less liquid, more CO2 needs to escape to maintain equilibrium, leading to the soda going flat [4:1]
[4:2]. The increased air space allows gases to expand more easily, facilitating the loss of carbonation
[4:3].
Temperature Effects
The solubility of gases like CO2 decreases with rising temperature. Shaking a soda can slightly increase its temperature due to friction, making it easier for CO2 to come out of solution [5:4]. However, this temperature change is minimal and not the primary reason for fizzing
[5:9].
Understanding these factors can help manage soda carbonation and prevent it from going flat too quickly.
Because it's dissolved in the liquid, and it comes out of the liquid easiest where there's already a gas-liquid boundary, if a high energy CO2 molecule is very near the surface it can escape into the gas phase, but if it's still in the middle of the liquid it will just hit a water molecule or something, randomly bouncing around.
when you crack open a soda, all that gas you hear hissing out isn’t just sitting there waiting. most of it is dissolved inside the liquid, kind of hidden between the water molecules. when you release the pressure, the gas wants to escape, but it can’t just vanish instantly. it needs spots to collect into bubbles first. that usually happens on tiny scratches in the bottle, dust particles, or even the sides of the glass. once the bubbles form, they rise up and release the gas little by little. if everything came out at once, the drink would basically explode in your face, but because it takes time for bubbles to grow and detach, you just get a steady fizz instead.
This is also the premise on how Mentos work. They provide thousands of pockets where this process is called, nucleation.
As a side note, this is how water boils as well. When water reaches 100c it wants to boil, it requires imperfections to create those bubbles of vapor to form. This is why new containers like Pyrex can spontaneously boil when you stick something in them. They are nearly perfectly smooth and once you introduce a fork or other utensil, it boils rapidly around it. This usually occurs when heating something in the microwave.
Oh interesting... So how does shaking a drink affect this process?
shaking a drink basically loads it with ready-made bubbles. normally the gas has to slowly find spots to form bubbles before it can escape, but shaking forces a ton of little bubbles to appear all through the drink. when you open it after that, the gas doesn’t wait around, it latches onto those bubbles right away and rushes out, which is why it foams up and spills.
The closed soda has a bunch of CO2 (usually) in the space between the top of the can and the soda itself. When you shake the can, you get a lot more of that gas dissolved in the soda than there would normally be. when there is too much CO2 dissolved in the soda, it really wants to come out. So, when you release the pressure by opening it, that gas will come out quickly.
So if you get some carbonated water in a clean room and pour it into a perfectly smooth glass, it'll stay fizzy longer?
And of course the wrong answer, but supremely confident and realible sounding, is sitting at the top.
why don't you share the correct answer if you're so confident mine is wrong?
I agree with what has been said, but one thing not mentioned is that carbon dioxide actually reacts with water to produce carbonic acid in solution:
CO2 + H2O <==> H2CO3
Note the double headed arrow that shows that the reaction is reversible. This acid then loses a hydrogen cation (proton) to produce bicarbonate anions:
H2CO3 <==> HCO3- + H+
To a lesser extent, the bicarbonate can also lose another hydrogen cation to produce carbonate anions.
HCO3- <==> CO3-- + H+
All these reactions are reversible, and under carbon dioxide pressure, an equilibrium concentration of carbon dioxide, carbonic acid, bicarbonate, carbonate, and hydrogen cations is formed in the water. This explains why carbonated water solutions have pH less than 7.0 (acidic), why carbon dioxide is more soluble in water than other gases, and at least partially why it takes longer for the gas to come out of the water.
Edit: Fixed carbonate anion formula
Ultimately the rate of any chemical process is going to depend on the activation energy - basically the energy required to break old bonds so the process can proceed. When a gas is dissolved in a liquid, there are intermolecular forces holding it in there, and in order for it to escape, it needs enough energy to break those forces.
At any given point in time, only a fraction of the dissolved gas molecules have enough energy to escape, so the gas comes out fairly slowly. If you raise the temperature though, more gas molecules will have enough energy, so it comes out faster.
You'll probably also notice that shaking a bottle or otherwise agitating it can help make it come out quicker. This is because the activation energy for the gas escaping the liquid and forming a bubble is not the same everywhere. Rough surfaces with more surface area may tend to lower the activation energy by "sticking" to the dissolved gas, helping it to come out of the liquid. Agitating the bottle can introduce air bubbles, which act as those rough surfaces.
Shaking it increases the amount of surface area between the gas and the air, which lets the CO2 in the liquid reach equilibrium with the gaseous CO2 more quickly. If you shake a bottle that's been sitting sealed for a few days, and let the bubbles rise back to the top before opening it, it will be the same as if you hadn't shaken it.
If there are a lot of bubbles still in the liquid when you open it, those will expand, and increase the surface area for more CO2 to come out of solution, causing the drink to spray everywhere and go flat very quickly.
do u mean when u open it up right after shaking? it should remain fuzzy if u just leave it. has to do with Co2 and equilibrium.
https://www.youtube.com/watch?v=K-Fc08X56R0&t=743s should hlep u understand it a bit more. specifically the part with the bottle of soda.
Yes, that's what I meant. Thanks!
Cody's Lab on youtube did a video on carbonated water the other day. I think that would also help to watch.
"Bad" is relative. I love flat cola, I bet many others do too.
Some small pharmacies sell "Coke Syrup" which is literally Coca Cola without the seltzer. It's been used for decades as a medicine to settle your stomach.
Carbonation adds that zing, making it way more enjoyable.
Cause of bubbles pop pop pop
If you only drank coke with no carbonation, you would likely assume it was better than coke with carbonation because it’s what you’re used to. Vice versa
Letting pop go flat means letting all of the carbonic acid turn into water and CO2, and letting all the CO2 leave.
It impacts the taste two ways - you lose the acid, which balances the sugar in the pop, and you lose the fizz, which impacts how it feels in your mouth.
Gasses compress a lot easier than liquids. When the bottle is full the bubbles pop and fill the small amount of space in the top of the bottle, until there is enough pressure to prevent further bubble popping. When the bottle is nearly empty there is a lot more room for the gasses to expand into.
More air in the bottle means more room foe the carbonation to dissipate in to it.
the air in the bottle
The ratio of liquid to air in the bottle at that point is very low. Air compresses; the soft drink doesn't (not in any meaningful measure, as far as this is concerned). So when the bottle is full, only a little bit of carbon dioxide can escape before the pressure is high enough to keep the rest of it in the drink. But as the volume of drink gets lower, more and more escaping CO2 is required to reach that level of pressure. Eventually, you run out of CO2
Before you open the can, there is carbon dioxide gas under pressure on top of the liquid, and it's in equilibrium with carbon dioxide gas dissolved in the liquid.
If you open the can without shaking it, that CO2 just escapes directly into the air, and the gas dissolved in the liquid can only really come out at the existing liquid-gas boundary.
If you shake the can first, you get a ton of bubbles inside the liquid that expand when you release the pressure, and if that wasn't enough, it also provides more surface area for the CO2 dissolved in the liquid to transition into gas, growing the bubbles further.
If you shake the can, and then wait a couple minutes before opening it, those bubbles will rise back to the top, and you can open it without issue.
Shaking the can before it's opened does not significantly change the temperature or pressure.
Flicking the side of the can will help dislodge bubbles there, but it's not relevant to shaking a can, as the shaking will dislodge those bubbles even better than flicking the side of it will. The bubbles form there when changes in temperature make the liquid unable to hold onto as much gas. (if you've opened a can of soda that's hot, and it sprayed everywhere even without shaking it, this is a big reason why)
minor correction, any flicking or tapping the can does nothing directly, thats a myth. It only doesn't fizz up afterwards because you let the can rest for the time period of your tapping instead of opening it directly.
Tested by this guy https://www.youtube.com/watch?v=r6tLeYJQS58
I think that agrees with what I said.
I once stored a couple 2L bottles of Pepsi in a cupboard above an oven. Later that night one of them finally gave up (probably had a weak spot in the plastic) and exploded. We never did get it all off the ceiling.
Bubbles like to form around surface defects or by enlarging existing bubbles. Shaking adds lots of existing bubbles.
Fun fact: mentos have lots of surface defects, which is why mentos make cola fizz up.
To be slight;ly techical, it take energy to form a new surface such as a bubble. While overall in a fizzy drink this is not a problem as there is lots of energy in the pressurized gas in the water. However if the existing bubble is too small or nonexistant the energy gain is too small to get the bubble to grow. By introducing lots of air bubbles in the drink by shaking you have lots of larger bubbles for the dissolved gas to escape to
TIL
Solubility of gasses is affected by temperature. Shaking a fizzy drink increases temperature enough duo to friction to allow gas to come out of solution.
Additionally mixing the drink with thr bit of air in the top adds little bubbles that can act as nucleation spots for more gas to be pulled out of solution.
The temperature rise is *extremely* small, isn't it?
When you shook it it fizzed up, it expanded but it's contained. When you open it it has somewhere to expand to.
It was already fizzed just couldn't move.
Shaking spreads tiny bubbles all through the liquid. When you open the bottle, the pressure inside drops suddenly, and those bubbles give the dissolved carbon dioxide gas an easy place to escape. The gas rushes out, pushing liquid with it, which is why it fizzes and can overflow. If the drink isn’t shaken, there are fewer bubbles for the gas to collect on, so it escapes more slowly.
It's kind of like letting 10,000 hungry weasels loose in a giant ball pit in the basement, behind a closed door. Of course, when you open the door a bunch of weasels will get loose, but not ALL of them, just the ones who happened to be near the door at the time, rolling around in the ball pit. Every time you open the door, more weasels will get loose in your kitchen, but not all of them at once, because they can't all fit right by the door, they scamper around at random. As more get loose as you keep closing and opening the door, there will be fewer and fewer weasels left, and your soda will be flat, all balls and no more weasels.
If you get them all riled up and open the door, more weasels will get loose at once, and a bunch of balls will probably spill out on the floor too.
There are about 10,000 molecules of water for each molecule of CO2 in soda. And there are two mechanisms that CO2 leaves soda, as individual molecules on the surface, or through visible bubbles that form inside the liquid. Either way, the CO2 molecule has to get past quite a bit of water molecules to either get to the surface, or get to a bubble, where it will be ejected.
It starts to immediately, just takes time... unless you put a mentos in it. Then nucleation points allow all the gas to escape quicker
It is mixed in and compressed. It keeps releasing with each bubble- basically.
I decided to pop this into google and there was a link on physics stack exhange that provided a very in depth explanation - I’ll try to summarize it here, but I’d recommend going there for a deeper explanation.
Basically CO2 leaves because as mentioned by the ccii_geppato, it’s mixed in and compressed and gets slowly released when the pressure decreases upon opening
The gas diffuses though the liquid slowly however, and there is an energy barrier that needs to be overcome in order to form a bubble at all. Often because the can is imperfect it lends itself to forming these bubbles. These are the reasons for the “slowly” part and not all at once.
Edit: I assume if everything was perfect and there was no uneven distribution or imperfections you might just have an open can that sits there with all of the CO2 inside of the soda in a supersaturated state. But the world is imperfect and constantly moving, and an open can is pretty easily disturbed.
Your title implies it's a constant rate of loss.
That won't be the case - hence the wording in the article.
> a loss of some 15–16% of gas may be expected to occur within 8 weeks of bottling.
Not every 8 weeks, just the first 8.
One is too long and technical for anybody to care about, the other simplifies it so that it fits the sub. Idk why everything needs to be so technical with trivial fun facts like this. “Plastic soda loses CO2 because of plastic” “cool learned something today 👍🏼”
My grandparents used to stock 2 liters of soda in the pantry for when we would visit as kids. Loved them dearly but it was always flat by the time we got there.
Can for permeability, glass for flavor.
But what is lost in carbonation is gained in microplastics.
Don't worry, you'll get your microplastics from glass bottles too
The plastic isn't the bottle material, or the cap material, it's nylon which is used for the cleaning brushes of reused bottles
I FRIGGIN KNEW IT.
Give me glass coke every day
And with real cane sugar, not corn syrup.
Well it's high fructose corn syrup, which is ~45% fructose and ~55% glucose.
Sugar being sucrose, which is 50% fructose 50% glucose, linked by a glycosidic bond.
Functionally, when it comes to dietary outcomes, there is very little difference between the two if you have a healthy diet and have sugars contribute to less than 10% of your caloric intake. However if you have an unhealthy diet high in saturated fats, trans fats, processed foods, and have the average 20% or more of your caloric intake coming from sugars like the average american, there is valid reasoning behind the idea that sucrose being a marginally less harmful option than HFCS.
However, making a choice between the two out of health concerns is flawed logical reasoning. I'm sure there are multiple fallacies, but the big one that sticks out to me is it's a false dilemma, and you can actually just choose to not consume any coke at all, or choose an alternative drink that you enjoy that doesnt contribute to an already bad diet.
Edit: Yes anyone who has any specific gastrointestinal issues the difference may be significant. Also some of you in the comments have severely outdated understands that were assumptive and proven to be false or inconclusive
Glass was so much better. Taste, longer lasting, recycling.
>Shelf-life of carbonated drinks in PET is shorter than for products packaged in glass or cans. This is due to the loss of CO2 through container walls. For a typical 2 l PET bottle weighing 43 g, a loss of some 15–16% of gas may be expected to occur within 8 weeks of bottling. For a 250 ml bottle, this loss may be expected to occur within 6 weeks. CO2 loss may be further minimised by incorporating into the PET, at a cost premium, other polymers with better gas retention characteristics. Oxygen ingress can also occur with corresponding deterioration of product.
That's not at all what it says.
Typical TIL post where the TIL is immediately disproven by the top comment.
How could I keep a limited time soda from going flat if I wanted to keep it for like 10 years
You open the container you bought it in, and pour the soda into a container that can be vacuum sealed for longterm storage. Retail soda containers such as cans or bottles cannot store carbonated beverages indefinitely, as the CO2 leaks out slowly within a few years.
Couldn't you just vacuum seal the can then?
The pressure inside of a soda is much greater than outside of a soda, and the pressure is what keeps it carbonated over time. Without pressurizing the outside of the can to be equal to the pressure inside the can, it will still go flat over time.
What package?
Soda in cans can usually end up leaking. Soda in plastic bottles usually contorts. Glass bottles stay about the same.
Eventually the carbonation will break down.
If you want to keep a can looking sealed make two holes in the bottom. One to let air in and one to let soda out.
With plastic bottles you might be able to try making colored water a similar color as the soda.
Glass bottles can probably last forever. I have a bottle of Dr Pepper from 1969 and it looks about the same, just somewhat lighter in color.
> I have a bottle of Dr Pepper from 1969
When you gonna drink it? :)
Not that brave.
I remember back in the days, when pouring coca-cola into cup, more than half of the cup will be filled up with fizzly bubble first and slowly dissipate away before can pour again. These days continously pouring, its just a thin layer of fizz....
What happened?
Great question. Have you always lived in the same place? I ask because b/c I notice Coke having different characteristics (carbonation, bite, etc.) in different parts of the US. Perhaps that is intentional, perhaps that is a variation driven by different bottlers or production lines. I also notice a carbonationbdifference between Coke that comes from a can vs. a plastic bottle.
Barometric pressure, maybe? Something high up would make the coke go flat faster
I've lived at 10k feet above sea level and can confirm. Carbonated beverages get flat noticably faster
I’m literally (and I mean literally!) 40 feet above sea level and my Diet Coke has so little fizz anymore. It’s not altitude.
I've lived in the same place and notice the same thing. Could also be that I don't drink it as often and am simply misremembering how it used to be. Like I feel I could open a can drink half, leave it in the fridge and come back to it being fizzy the next day. Now it'll be hella flat
My wife's diet coke used to last hours once opened and now goes flat in minutes. No difference in location, pressure, climate, etc.
The only factor we can identify if the DC itself.
It depends on the residue of what the glass was washed with. That is a serious "release" reason for the CO2.
I find that the more it fizzes when I pour it. The flatter the drink after, because all the gasses have been released. I try to pour it slow against the side of the glass (like im pouring a beer) to preserve as much carbonation as possible.
I stopped pouring my beer like that so I could get as much carbonation out of it as possible. I'll wait for the head to settle.
Also the type of glass. That's why some pubs have special beer mugs, to get the fizz just right.
Yup. Im hour drive from the states. I notice all the drinks from Walmart. Cokecola, Pepsi, 7up all taste different and flat. Soda are still ok at my Canadian Walmart.
They halved the bubbles in each bottle. Shrinkflation......
Okay so today I opened a can of soda and left it on the table while I made lunch. When I opened it it fizzed up the normal amount and went down. About 2 minutes go by with the soda sitting there undisturbed and normal when I hear a loud fizzing sound and I see the soda begin to refoam and then spill over. I had never seen anything like that before and was pretty freaked out and would have thought I was crazy if my brother hadn't also witnessed the event. Having no idea what caused it and being a little afraid to drink it we grab another soda and open it and decide to watch to see if that soda was just weird or if all of them would do that. The second one opens normally and we watch it for about a minute and a half of it just sitting there like a normal soda when it goes CRAZY like even more than the first one i barely even had time to grab a paper towel before it made a complete mess. The soda ended up being fine to drink but I'm still pretty weirded out. Could it be something with the temperature or the air pressure? Or am I drinking some freak soda.
They may have had one of those nitrogen widgets in it like a can of Guinness. Either that or your brother snuck an alka seltzer in there when you weren’t looking.
It was just a cheapo generic brand cola so no widget. Also on the second can I never took my eyes off it so not that either 😭
i need to know why
why does soda go flat
Key Considerations on Why Soda Goes Flat:
Carbonation Process: Soda is carbonated by dissolving carbon dioxide (CO2) gas under pressure. When you open a soda, the pressure is released, allowing CO2 to escape.
Temperature Effects: Warmer temperatures decrease the solubility of CO2 in liquid. As soda warms up, it loses carbonation more quickly, leading to flatness.
Exposure to Air: Once opened, soda is exposed to air, which allows CO2 to escape more rapidly. The more the soda is agitated or poured, the faster it goes flat.
Container Type: The type of container can affect how quickly soda goes flat. Cans and bottles with tight seals retain carbonation longer than cups or open containers.
Time: The longer soda is left open, the flatter it will become. Even in a sealed bottle, over time, some CO2 will naturally escape.
Takeaway: To keep soda fizzy for longer, store it in a cool place, keep it sealed tightly, and minimize exposure to air. If you want to enjoy your soda at its fizziest, try to consume it soon after opening!
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